Diluting a solution does not change the amount of solute, so c₁V₁ = c₂V₂. This finds the final volume needed and how much solvent to add.
When you dilute a solution, the amount of solute does not change. Only the solvent increases. That single fact gives the dilution equation.
Both sides are the amount of solute in moles. The equation says nothing more than that this amount is the same before and after.
Dilute 100 mL of a 2 mol/L solution down to 0.5 mol/L.
The final volume must be 400 mL, so you add mL of water.
The concentration fell to a quarter and the volume rose fourfold. Concentration and volume are inversely proportional.
Always add acid to water, never water to acid.
Concentrated sulfuric acid releases a great deal of heat when it meets water. Pour water onto the acid and the droplet flashes to steam, spitting concentrated acid out of the vessel. "Do as you oughta, add acid to water."